
October 15, 2008 FONTIERS IN MATERIALS SCIENCE VINSE COLLOQUIUM SERIES Dr. David Norris University of Minnesota "Tailoring the Glow of a Heated Metal: Photonic Crystals and Thermophotovoltaics"
Abstract. Photonic crystals are materials that are patterned on an optical length scale. When these structures are heated, their “glow” (or thermal emission) can be modified due to optical interference. This may allow the elimination of unwanted heat from thermal emission sources, such as the tungsten filament in a conventional light bulb. Furthermore, this effect may lead to efficient thermophotovoltaic devices. The generation of electricity from sunlight is hindered by the energetically broad distribution of solar photons. Because standard photovoltaic devices transform these photons into isoenergetic electrons, energy mismatches lead to waste. While many approaches aim to improve this direct photon-to-electron conversion, a less-studied alternative is to transform sunlight first into low-energy photons. A material, heated by the sun, can thermally emit infrared light that is matched to a photovoltaic cell. In principle, this thermophotovoltaic process can be efficient, but has been limited by the emission spectra of real materials. Because of their ability to tailor thermal emission, metallic photonic crystals can provide an interesting new class of thermophotovoltaic emitters. In this talk, we will discuss the fabrication of metal structures and the measurement of their thermal emission, in particular for thermophotovoltaics. We will demonstrate molybdenum photonic crystals that, when heated to 650°C, should generate over ten times more power than solid emitters while having an optical-to-electrical conversion efficiency above 32%. At such relatively low temperatures, these emitters have promise not only in solar energy but also in harnessing geothermal and industrial waste heat. |
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